Aegle Marmelos or Bel Leaves are used in the rituals related to Lord Shiva. What is the significance of these leaves in Hinduism?
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The reason that the leaves of the Bilva tree are used in the worship of Shiva is that the Bilva tree emerged from the sweat of Shiva's wife Parvati, as described in the this excerpt from the Nagara Khanda of the Skanda Purana:
Those are all names of different forms of the goddess Parvati. Since every part of the Bilva tree is suffused with some form of Parvati, it is the ideal article to be used in worship of Shiva, just as Tulasi is ideal for worshipped Vishnu as it's associated with Vishnu's wife Lakshmi.
There is a stotra (hymn) called Bilwastakam, that describes the spiritual benefits of using even one bel leaf for lord Shiva. For example, the first verse says:
So basically, the bel leaves used in Shiva puja signify the three eyes of Shiva and also His three pointed trident (or three weapons). Hence, bel trees, being a favorite of shiva, are also considered to be a form of Shiva as well (mahādevasvarupoyaṃ bilvo [Shiva Puran 22.22]).
The bilva tree itself is so holy and auspicious that its worship or its significance is mentioned in many puranas and other scirputres at various instances. Here below is a narration of "greatness of bilva" under 22nd chapter in vidyesvarasamhita of shivapurana.
Born from the breasts of Goddess Lakshmi, the Bilva tree is ever dear to Mahadeva. So I ask this tree to offer a Bilva leaf to Lord Shiva. To have darshan of the Bilva tree, and to touch it, frees one from sin. The most terrible karma is destroyed when a Bilva leaf is offered to Lord Shiva.Sri Bilva Shtakam (v. 6–7)
The proportion of sattva component is more in bilva patra and hence it has more capacity to absorb and emit sattvik frequencies. This has various effects. One of them is the reduction of raja-tama particles present in the atmosphere. A sattvik leaf like bilva patra when brought in proximity of a person suffering from negative energy distress then the black energy present within him is reduced.